Abstract

We have demonstrated an effective strategy on the nitridation process to synthesize ε-Fe3N nanoparticles (NPs) from the zero valent iron NPs as a starting material. The transformation of iron into iron nitride phase was systematically studied by performing the nitridation process at different processing temperatures. The phase, crystal structure was analyzed by XRD. Morphology and size of the ZVINPs and ε-Fe3N NPs were analyzed by field emission scanning electron microscope. Further, their room temperature magnetic properties were studied by using vibrating sample magnetometer and it revealed that the magnetic property of ε-Fe3N is associated with ratio of Fe-N in the iron nitride system.

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