Optimization of preparation of NaA zeolite from fly ash for CO2 capture.

Abstract

The green synthesis method of fly ash-based NaA zeolite was explored to reduce the synthesis cost and environmental hazards. For the prepared NaA samples, the effects of crystallization time, solid-liquid ratio, and Si/Al ratio were systematically studied. CO2 adsorption isotherm is used for adsorption model fitting analysis and adsorption selectivity determination. According to the experimental results, the optimized NaA zeolite synthesis conditions are as follows: the Si/Al ratio of NaA zeolite is 1.4, the solid-liquid ratio is 10, and the crystallization time is 6 h. The green synthesis method reported in this study can successfully prepare NaA zeolite and exhibit excellent CO2 adsorption performance, reaching 4.34 mmol/g, with high CO2 selective adsorption ability, reaching 89.2 for N2, 257.1 for O2, and 45.8 for CH4. The adsorbed CO2 can be released for further utilization, and NaA zeolite also has strong adsorption and regeneration performance, with a ten cycle adsorption capacity only decreasing by 1.17%. In addition, the use of cheap raw materials synthesis methods will promote the large-scale industry application of green synthesis technology in the future.