Optimization of nitrogen removal from piggery waste by nitrite nitrification

Abstract

The piggery waste characteristics greatly vary with types of manure collections and the amount of water used. If solids are separated well, the waste strength will be greatly reduced resulting in lower TCOD/TKN ratio of 4 (average). If solids are separated by a mechanical scraper, some solids will remain and the waste strength will be increased with a TCOD/TKN ratio of 7. This study was conducted to find an optimum operating condition for nitrogen removal with these two ratios. Nitrite nitrification was targeted because it could be a short cut process for savings in oxygen for nitrification and carbon requirements for denitrification. The study results indicated that nitrogen loading rate and pH were the most important factors to be considered for stable nitrite nitrification. The applicable nitrogen loads were estimated to be 0.3 to 2.0 kgTKN/oxic m3/d for high TCOD/TKN ratio without pH control. With higher pH > 8, NO2N/NOxN ratios in oxic stages even with lower nitrogen loads were increased. The SBR with low TCOD/TKN ratio less than 4 required additional alkalinity. For a complete denitrification, the influent TCOD/TKN ratio must exceed 6 with oxic/total reactor volume ratio of 0.5. Nitrite nitrification and denitrification could save about 35% in tank volume and 50% in carbon requirement, respectively. However, 9.5% oxygen saving could be expected during the operation with low TCOD/TKN ratio. The elevated temperature due to the heat released from COD removal also enhanced microbial activities for nitrification and denitrification as well as ammonia stripping. However, careful attention must be provided for the reactor temperature not to inhibit the nitrification process.