Optimization of membrane thickness for proton exchange membrane electrolyzer considering hydrogen production efficiency and hydrogen permeation phenomenon

Abstract

Reducing the membrane thickness of Proton exchange membrane (PEM) electrolyzer was found to efficiently promote the hydrogen production rate. However, it can also aggravate the phenomenon of hydrogen permeation, leading to an increased hydrogen content on the anode side and posing a risk of explosions. Thus, optimal design of the membrane thickness of PEM electrolyzer systems is crucial to ensure both safe and efficient hydrogen production. In this paper, we propose two optimization problems for the membrane thicknesses, aiming at achieving a balance between the hydrogen content on the anode side and the hydrogen production rate under constant and varying power input conditions. First, the theoretical model of a PEM electrolyzer is established, and a photovoltaic-PEM electrolyzer system is considered to provide varying power input conditions. Then, the two optimization problems are formulated and resolved using the sequential quadratic programming (SQP) and particle swarm optimization (PSO) algorithms, respectively. Our results reveal that the optimal membrane thickness decreases as the constant input power increases. This suggests that high/low power inputs require thin/thick membranes. For varying power input, we collected one year of solar radiation intensity data from four different regions in China. The findings demonstrate that the selection of the optimal membrane thickness depends not only on the average solar radiation intensity but also on its seasonal variations. By applying these strategies, we effectively optimize the membrane thickness in PEM electrolyzer systems, thereby enhancing the efficiency and safety of hydrogen production. The outcomes provide valuable insights for selecting the appropriate membrane thickness in regions with varying solar radiation intensities and accounting for seasonal variations in solar radiation.