Abstract
New fluorite-type anion excess phases have been prepared within the PbF 2M'F 3-ZrF 4 (M'=In, Bi) systems involving simultaneously trivalent and tetravalent cations. The materials showing the highest ionic conductivity are characterized by presence of column clusters of (n=2) size and by values of the Zr/In and Bi/Zr ratios close to 1 2 . The obtained results are discussed on the base of a previously set up clustering model.
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