Optimization of critical current density of bulk YBCO superconductor prepared by coprecipitation in oxalic acid

Abstract

YBa2Cu3O7−x(YBCO) superconductor powder was prepared from mixtures of solutions containing yttrium, barium, and copper nitrates by coprecipitation in oxalic acid. Single-phase YBCO was obtained from a solution mixture of 14 vol% excess of barium nitrate and 12 vol% excess of copper nitrate relative to the stoichiometry of YBCO. The optimal pH in the coprecipitation process was determined to be 6.6–6.7 which was obtained by using 12 vol % excess oxalic acid anhydrous solution of the required oxalic acid to convert all metal cations to oxalates and adding a dilute ammonium hydroxide solution. The measurement of critical current density, J c, of bulk YBCO prepared by the coprecipitation, showed a trend that the J c increased together with the degree of orthorhombic distortion of YBCO phase which depended on the sample density and the content of impurity phases.