Abstract
AbstractA series of iron intercalated montmorillonites (Fe‐Monts) were prepared using (i) ion exchange of native sodium and calcium ions with iron ions, (ii) base hydrolysis of inserted iron ions in montmorillonite suspension, and (iii) insertion of pre‐hydrolyzed iron colloid in montmorillonite. The materials were characterized by X‐ray diffraction and gas adsorption‐desorption techniques. The basal d(001)‐spacing and BET specific surface area increased after the intercalation of iron species in montmorillonite. Local iron structure studied by X‐ray absorption fine structure (XAFS) spectroscopy showed an unsaturation of the Fe···Fe coordination number (N 2.5) of the intercalated iron species as compared to the bulk iron oxyhydroxides (N 6). The Fe‐Monts were employed for arsenic removal from aqueous solutions at low concentration (0.2–16 mg/L). Among the Fe‐Monts, the one prepared by the hydrolysis of inserted iron ions, was the best in performance. The saturation adsorption amount of the optimized iron‐montmorillonite was 4 and 28 times higher for the removal of arsenite and arsenate, respectively, as compared to bulk iron oxyhydroxide (goethite). Compared with bulk iron oxyhydroxide, the Fe‐Monts were superior for arsenate uptake and comparable for arsenite. In addition, arsenite adsorbed on the Fe‐Monts was found to be oxidized to arsenate based on XAFS spectroscopy.
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