Abstract

This study determines the optimum temperature for the alkali fusion process used to effectively separate iodine from solidified radwaste attaining low-level 129I by neutron activation. The alkali fusion temperature was adjusted to 120, 200, and 400 °C to approach the optimum conditions associated with a good statistical distribution of the measured 129I data and high chemical recovery yield. Statistical analysis revealed that the optimum temperature of the alkali fusion process was 200 °C, displaying good central tendency and low variance of the measured 129I data, and the respective chemical recovery yields were higher than other temperatures. The optimum fusion condition provides more reliable scaling factors (129I/137Cs) of radwaste.

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