Optimization of a heterogeneous catalytic hydrodynamic cavitation reactor performance in decolorization of Rhodamine B: Application of scrap iron sheets

Abstract

A low pressure pilot scale hydrodynamic cavitation (HC) reactor with 30L volume, using fixed scrap iron sheets, as the heterogeneous catalyst, with no external source of H2O2 was devised to investigate the effects of operating parameters of the HC reactor performance. In situ generation of Fenton reagents suggested an induced advanced Fenton process (IAFP) to explain the enhancing effect of the used catalyst in the HC process. The reactor optimization was done based upon the extent of decolorization (ED) of aqueous solution of Rhodamine B (RhB). To have a perfect study on the pertinent parameters of the heterogeneous catalyzed HC reactor, the following cases as, the effects of scrap iron sheets, inlet pressure (2.4–5.8bar), the distance between orifice plates and catalyst sheets (submerged and inline located orifice plates), back-pressure (2–6bar), orifice plates type (4 various orifice plates), pH (2–10) and initial RhB concentration (2–14mgL−1) have been investigated. The results showed that the highest cavitational yield can be obtained at pH 3 and initial dye concentration of 10mgL−1. Also, an increase in the inlet pressure would lead to an increase in the ED. In addition, it was found that using the deeper holes (thicker orifice plates) would lead to lower ED, and holes with larger diameter would lead to the higher ED in the same cross-sectional area, but in the same holes’ diameters, higher cross-sectional area leads to the lower ED. The submerged operation mode showed a greater cavitational effects rather than the inline mode. Also, for the inline mode, the optimum value of 3bar was obtained for the back-pressure condition in the system. Moreover, according to the analysis of changes in the UV–Vis spectra of RhB, both degradation of RhB chromophore structure and N-deethylation were occurred during the catalyzed HC process.