Abstract
AbstractA mathematical model for the free radical batch solution polymerization of methyl methacrylate that takes depropagation into account was developed. This model was then used to derive optimal temperature and initiator concentration policies to reduce residual monomer concentration to desired levels, producing at the same time a polymer with the desired number average molecular weight. An objective function was formulated to take account of the cost of the initiator with respect to the cost of time of reaction. It was observed that when the cost of initiator increased, optimal initiator concentration decreased whereas optimal temperature increased. Finally temperature reached a limiting value above which polymer with desired number average molecular weight could not be produced. These results give insight into the factors that determine the policies that could be employed in optimizing the operation of a reactor.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
