Abstract

The potential of power-to-ammonia is increasingly recognized as a large-scale renewable electrical energy storage technology in the energy-transition landscape. Unlike conventional, continuously operating Haber-Bosch production processes, power-to-ammonia processes face operational challenges stemming from fluctuations in renewable power supply. Systematic strategies that can adapt to these fluctuations are required to improve the operational flexibility and stability of power-to-ammonia processes for industrial applications. This study proposes a multi-stable flexible ammonia operation strategy, which is practical and feasible in engineering. To maximize net profit, a design scheduling coordination optimization model is established and solved using a two-stage algorithmic framework of particle swarm and mixed integer linear programming. Additionally, three flexible scenarios are designed for the simulation analysis of a grid-connected green ammonia system. Compared with the traditional constant inflexible scenario, the multi-stable flexible scenario increases annual net profit by 5.05 M$ and reduces carbon emission intensity by 1.61 kg CO2/kgNH3. Furthermore, compared with the continuous flexible scenario, the volatility of the ammonia production load is reduced by 79.89 %. The multi-stable flexible operation strategy balances the green ammonia system’s economic, safety, and low-carbon attributes. Sensitivity analysis reveals that wind and photovoltaic complementary power generation reduces green ammonia costs and carbon emissions. When the selling price of ammonia exceeds 550 $/t, ammonia production and sales should be prioritized, but at lower ammonia prices, selling electricity to the grid to optimize economic efficiency is advised. This study provides novel insights into the flexible operation of the power-to-ammonia process and is expected to offer guidance for constructing and operating green ammonia systems.

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