Optically transparent and thermally stable nonlinear optic chromophores featuring a thieno[2,3- b]thiophene donor

Abstract

A thieno[2,3- b]thiophene core has been utilized as a π-donor component to design two series of push–pull thienothiophenes by introducing various acceptor groups either via olefinic or aza-spacers. The molecules show a UV–visible cut-off wavelength below the second harmonic generation (SHG) at λ/2 of 532 nm, thereby conforming to the nonlinearity–transparency trade-off. Second order molecular nonlinearity, β measured by Hyper-Rayleigh scattering technique was found in the range of 9.58–47.66×10 −30 esu, while the Kurtz powder technique produced signals of the order of 0.43–1.02 U. Thermal decomposition temperatures measured by differential scanning calorimetry revealed decomposition temperatures≥275 °C, indicating high thermal stability.