Abstract
Well-defined exchange splittings of the R lines of Cr3+ in Cr2O3 have been observed in absorption at low temperatures. The majority of the transitions originate on the lowest (Ms=−32) component of the A24 (ground) state and terminate on the four (exchange split) components of the two E2 levels. The lines show strong polarization effects, the outer two components of the four line group appearing in the perpendicular spectrum (E⊥c axis) and the inner two components appearing in the parallel spectrum. From the observed polarizations and from relative intensity measurements the identity of each of the components has been deduced. On the basis of the identifications made, the exchange splitting of the R1 doublet is approximately 183 cm−1 and that of the R2 doublet is approximately 139 cm−1. A ground-state splitting of 245±20 cm−1 is obtained from a weak line originating on the Ms=−12 (A24) level. The trigonal field (plus spin orbit) splitting of the E2 levels can also be deduced from the spectrum. The splitting would appear to be very small (of the order of 1 cm−1) compared with that of Cr3+ in ruby (29.6 cm−1) and of the opposite sign.
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