Abstract

Measurements of the three components of the birefringence of betaine calciumchloride dihydrate (BCCD) in the range from 170 to 30K are reported. Clear anomalies are observed at the normal-incommensurate transition and at the transitions which connect low-order commensurate phases. The birefringence remains, however, unsensitive to high-order commensurate phases, among them, the phase with q=27, in the range 127–125K. The critical behaviour of the spontaneous birefringence at the normal- incommensurate transition at 164K has been studied. The resulting critical exponent is 2β∼0.76. The possibility that this phase transition takes place in two steps with a narrow intermediate phase, as suggested recently, has been carefully examined. The existence of two separate anomalies could not be confirmed. In general, the present results are compatible with the conventional model of a single order parameter for the whole transition sequence.

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