Abstract

AbstractThe energies of the free exciton and of four excitons bound to neutral acceptors (A°, X) are determined by either reflection, absorption, or emission with high purity p‐type GaSb. The data give evidence that bound excitons may be described alternatively as an electron bound by a donor‐like A+‐centre. For one particular deep A+‐centre, transitions from neutral donor states to that A+‐centre are observed besides the bound exciton decay. p‐GaSb is especially favourable for observing deep A+‐centres, because of the position of the Fermilevel. Conditions under which they may be observable for other III–V compounds are discussed.

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