Abstract
Some peculiarities of the effect of enantiomers of the monodentate ligand on the stereoisomerism of the mixed octahedral tetrafluoride complexes of d0-transition metals are established by the 19F{1Н} and 31Р{1Н} NMR methods for the complex formation of TiF4 with Ph2P(O)CH2CH(OH)Me (L) having the asymmetric carbon atom in the aliphatic hydrocarbon radical and being a racemic mixture of enantiomers in СН2Сl2. The compositions of the complexes formed in solutions are determined. The conclusion about the relative stereochemical configuration of the chiral and meso-stereoisomers of the geometric isomers of the TiF4L2 octahedral complex is based on an analysis of the 19F NMR spectra using the heterotropic concept.
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