Abstract
Knowledge of the geometric and electronic structure of gold clusters and nanoparticles is vital for understanding their catalytic and photochemical properties at the molecular level. In this study, we report the vibronic optical photodissociation spectrum of cold and mass-selected Au4 + clusters measured at a resolution high enough to allow for comparison with Franck-Condon simulations of the excited state transitions based on time-dependent density functional theory calculations. The three vibrational frequencies identified for the lowest-lying optically accessible excited state at 2.17 eV stem from the Y-shaped isomer (C2v ) and not from the rhombic isomer (D2h ) considered to be the ground state structure of Au4 + . This study demonstrates that an analysis of low-resolution electronic spectra by calculations of vertical transitions alone is not sufficient for a reliable isomer assignment of such metal clusters.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
