Abstract
The optical properties of α-SiC before and after ex-situ hydrogenation have been investigated by absorption-, reflectivity- and ellipsometric measurements in the energy range 1.5eV < hv <24eV. Unlike for in-situ hydrogenated SiC films drastic changes in the dielectric function were observed, which can be explained by the formation of a surface carbon layer. The occurence of a strong plasmon at 6.5eV is related to the formation of sp 2 bonds between carbon atoms in the surface layer. Our investigations provide new insight to a new method for changing the optical and electronic properties of SiC, that is inert to most other widely used liquid etchants.
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