Optical properties of the quasi-two-dimensional dichalcogenides 2H-TaSe $ \mathsf {_2}$ and 2H-NbSe $ \mathsf {_2}$

Abstract

We present a comprehensive analysis of the optical constants of the two-dimensional dichalco- genide materials 2H-TaSe2 and 2H-NbSe2, in an attempt to address the physics of two-dimensional corre- lated systems. The title compounds were studied over several decades in frequency, from the far-infrared to the ultraviolet. Measurements with linearly polarized light have allowed us to obtain both the in-plane and out-of-plane components of the conductivity tensor. Although the electromagnetic response of dichalco- genides is strongly anisotropic, both the in-plane and out-of-plane components of the conductivity tensor share many common features, including the presence of a well-defined metallic component, as well as a "mid-infrared band". We discuss the implications of these results in the context of the spectroscopic results of other classes of low-dimensional conductors such as the high-temperature superconducting cuprates. In particular, the analysis of the redistribution of the spectral weight as a function of temperature, as well as the behavior of the quasiparticles relaxation rate, points to significant distinctions between the charge dynamics of dichalcogenides and other classes of low dimensional conductors.