Optical Properties of Nd Doped Lead Borotellurite Glass

Abstract

Many trivalent rare earth ions such as Er3+, Tm3+, Ho3+, Pr3+ and Nd3+ were doped as absorption and emission centers in glass hosts. In this work, lead borotellurite (PBT) glass doped with neodymium ion (Nd3+) has been prepared and characterized by mean of their optical properties. The UV-Vis measurement has been carried out in order to determine the optical band gap energy, reflective indices and the polarizability. Optical absorption spectra of the glass samples are recorded in the range 400–900 nm at room temperature From the result, there are six significant absorption peaks that corresponds to 525 nm, 584 nm, 683 nm, 747 nm, 805 nm and 878 nm wavelength have been observed with the most predominant peak to be used as excitation wavelength is found centered at 584 nm. The energy band gaps as well as the refractive indices were found to vary from 2.50eV to 2.59eV and from 1.89 to 1.96 with mol% of Nd content respectively. Meanwhile, the polarizability shows a similar trend of results to refractive indices as it varies from 5.56 x 10-24 cm3 to 5.63 x 10-24 cm3. These results will be discussed further in details.