Abstract

The tunability of the optical properties of small gold nanoparticles assembled from size-selected Au6-10 clusters on the surface of indium-tin-oxide glass support was studied as a function of gold particle size and shape using UV-VIS and dark-field microscopy techniques. The size and shape of gold nanoparticles was determined by employing synchrotron X-ray scattering. The obtained spectra show that a 350 nm wavelength range is accessible by proper tuning the size and shape of the studied nanoparticles with 1-2.5 nm main size and asymmetric vs symmetric form.

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