Optical properties of disperse-red-1-doped nematic liquid crystal

Abstract

We report on the optical properties of nematic liquid crystal cells containing the commercially available liquid crystal E7 doped with the azo dye Disperse Red 1 at concentrations ranging from 0.3% to 1.0%. From polarized absorption measurements an order parameter of S=0.569 was obtained, thus showing that the dye molecules align themselves very well with the liquid crystal's director axis. Optical index gratings were written in the material by overlapping two coherent laser beams at 532 nm. Self-diffraction of the writing beams and diffraction of a probe beam at 670 nm were measured. First-order self-diffraction efficiencies and rise times were found to be linearly dependent upon the dye concentration with a maximum efficiency of 3.29% and a minimum rise time of 10.6 ms. The non-linear index coefficient, n 2, was calculated to be 7.6 × 10-3cm2W-1. The data are consistent with a grating formation based on trans–cis photoisomerism of the dye molecules that leads to a reorientation of the liquid crystal phase. These photonic devices are functional without the application of any external field, they are easily prepared, and have lifetimes in excess of two years without any indication of degradation when stored at ambient temperature.