Optical Properties of Airborne Soil Organic Particles

Abstract

The impact of water droplets on soils has recently been found to drive emissions of airborne soil organic particles (ASOP). The chemical composition of ASOP include macromolecules such as polysaccharides, tannins, and lignin (derived from degradation of plants and biological organisms), which determine light absorbing (brown carbon) particle properties. Optical properties of ASOP were inferred from the quantitative analysis of the electron energy-loss spectra acquired over individual particles using transmission electron microscopy. The optical constants of ASOP are compared with those measured for laboratory generated particles composed of Suwanee River Fulvic Acid (SRFA) reference material, which is used as a laboratory surrogate of ASOP. The chemical composition of the particles was analyzed using energy dispersive X-ray spectroscopy, electron energy-loss spectroscopy, and synchrotron-based scanning transmission X-ray microscopy with near edge X-ray absorption fine structure spectroscopy. ASOP and SRFA...