Abstract

We report the optical properties of a new type of photonic crystal: a transparent fused silica matrix containing quantum dots—nanoparticles of another material. In this study, nanoparticles consist of graphite zones several nanometers in size, stabilized by zirconia. The photonic crystal is prepared by high-temperature annealing (1200°C) of synthetic opal infiltrated with zirconia and a small amount of carbon. We demonstrate selective reflection of visible light from the surface of the quantum-dot crystal under broadband illumination. Such crystals are potentially attractive as narrow-band selective filters that would reflect the exciting light in Raman measurements and might be used to convert short-wavelength broadband radiation to quasi-monochromatic light in the visible range.

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