Abstract
The temperature dependence of optical poling of a side-chain azobenzene–polyimide film with high glass transition temperature was experimentally investigated. With the increase of the sample temperature the light-induced second-harmonic generation increased first, and then decreased as the temperature was near its glass transition temperature. The light-induced second-order nonlinear optical coefficient d33 for the optimum temperature was determined to be 6.9 pm/V, which was about 2.7 times that obtained at room temperature. Compared with optical poling at room temperature, this thermal-assisted optical poling not only enhanced d33 of the polyimide film, but also improved the polar order stability of molecules. Optical storage based on optical poling was also demonstrated experimentally.
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