Optical Modification of a Nanoporous Alumina Structure Associated with Surface Coverage by the Ionic Liquid AliquatCl.

Abstract

This manuscript analyses changes in the optical parameters of a commercial alumina nanoporous structure (AnodiscTM or AND support) due to surface coverage by the ionic liquid (IL) AliquatCl (AlqCl). XPS measurements were performed for chemical characterization of the composite AND/AlqCl and the AND support, but XPS resolved angle analysis (from 15° to 75°) was carried out for the homogeneity estimation of the top surface of the ANDAlqCl sample. Optical characterization of both the composite AND/AlqCl and the AND support was performed by three non-destructive and non-invasive techniques: ellipsometry spectroscopy (SE), light transmittance/reflection, and photoluminescence. SE measurements (wavelength ranging from 250 nm to 1250 nm) allow for the determination of the refraction index of the AND/AlqCl sample, which hardly differs from that corresponding to the IL, confirming the XPS results. The presence of the IL significantly increases the light transmission of the alumina support in the visible region and reduces reflection, affecting also the maximum position of this latter curve, as well as the photoluminescence spectra. Due to these results, illuminated I-V curves for both the composite AND/AlqCl film and the AND support were also measured to estimate its possible application as a solar cell. The optical behaviour exhibited by the AND/AlqCl thin film in the visible region could be of interest for different applications.