Abstract
The ferric chloride doped polymers change their refractive index under UV irradiation. The Fe:PVA is sensitive to ferric chloride concentration, molecular weight of PVA, and recording beam power. By Mossbauer investigations we tried to correlate the Fe2+/Fe3+ ratio, as well as the temperature dependence of the energetical parameters with the assumed mechanisms which involve both the valence state of iron and a cross-linking reaction of PVA matrix.
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