Abstract

We report direct measurements of the frequency ratio of the 642 THz electric octupole transition in 171Yb+ and the 429 THz transition in 87Sr. A series of 107 measurements has been performed at the Physikalisch-Technische Bundesanstalt between December 2012 and October 2019. Long-term variations of the ratio are larger than expected from the individual measurement uncertainties of few 10−17. The cause of these variations remains unknown. Even taking these into account, we find a fractional uncertainty of the frequency ratio of 2.5 × 10−17, which improves upon previous knowledge by one order of magnitude. The average frequency ratio is . This represents one of the most accurate measurements between two different atomic species to date.

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