Abstract
Photoabsorption cross-section profiles have been obtained for closed-shell and open-shell ionized size-selected sodium clusters Na + 9, Na + 21 and Na + 11. The spill-out of the valence electron cloud explains the red-shifted collective excitation frequency with regard to the Mie frequency. Quantum-mechanical calculations may give energy positions of the resonant structures consistent with the experiment. However, the absolute parameters of the profiles suggest that some oscillator strength is missing.
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