Optical cooling of lead halide perovskite nanoparticles enhanced by Mie resonances.

Abstract

Halide perovskites are a family of semiconductor materials demonstrating prospective properties for optical cooling owing to efficient luminescence at room temperature and strong electron-phonon interaction. Moreover, perovskite based nanophotonic designs would allow for efficient optical cooling at the nanoscale. Here, we propose a novel strategy for the enhancement of optical cooling at the nanoscale based on optical resonance engineering in halide perovskite nanoparticles. Namely, the photoluminescence up-conversion efficiency in a nanoparticle is optimized via excitation of Mie-resonances both at emission and absorption wavelengths. The optimized theoretical photo-induced temperature decrease achieved for a hybrid halide perovskite (CH3NH3PbI3) 530 nm nanoparticle on a glass substrate is more than 100 K under CW illumination at wavelength 980 nm and moderate intensities (∼7 × 106 W cm-2). The optimized regime originates from simultaneous excitation of a magnetic quadrupole and a magnetic octupole at pump and emission wavelengths, respectively. The combination of a thermally sensitive photoluminescence signal and simplicity in the fabrication of a halide perovskite nanocavity will pave the way for implementation of nanoscale optical coolers for advanced applications.