Abstract
The present work reports the spectroscopic and thermo-optical properties of CdSe/ZnS and CdSe/CdS core–shell quantum dots (QDs) embedded in synthetic saliva. Spectroscopy studies were performed applying nonfunctionalized CdSe/ZnS QDs (3.4, 3.9 and 5.1nm cores) and hydroxyl group-functionalized ultrasmall CdSe/CdS core–shell quantum dots (1.6nm core) suspended in artificial saliva at different potential of hydrogen (pH) values. Saliva was chosen because it is important in a variety of functions such as protecting teeth through the buffering capacity of the formed biofilm, hydration, and dental remineralization. Thermo-optical characterizations using the thermal lens (TL) technique were performed in QD-biofluids for different QD sizes and pH values (3.9–8.3) of the synthetic oral fluids. Transient TL measurements were applied to determine the fluorescence quantum efficiency (η) in QD-biomaterial systems. High η value was obtained for ultrasmall CdSe/CdS QDs. Fluorescence spectral measurements of the biomaterials support the TL results. In addition, for nonfunctionalized (3.4 and 5.1nm) and hydroxyl group-functionalized QDs, the temporal behavior of the fluorescence spectra was accomplished about approximately 1200h at two different biofluid pH values (3.9 and 8.3). The temporal fluorescence intensity result is dependent on the pH of the saliva in which the QDs were embedded, QD functionalization and QD sizes. The time for an approximately 50% decrease in the peak intensity fluorescence of CdSe/ZnS QDs (3.4nm core) and ultrasmall CdSe/CdS QDs is respectively 25h and 312h at pH 3.9 and 48h and 360h at pH 8.3.
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