Abstract
In this work a novel material, fullerene‐Zn(II) tetraphenylporphyrin, is obtained and studied using UV‐Vis‐NIR absorption and Raman scattering methods. C60–ZnTPP thin films were produced by vacuum evaporation in hot‐wall reactor. The detection of the Ag2‐derived modes at 1460 and 1452 cm−1 in the Raman spectra manifests the charge‐transfer C60–ZnTPP complex formation. It is shown that additional absorption band at 1.38–1.53 eV observed in the films corresponds to the HOMO‐LUMO gap of C60–ZnTPP complex.
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