Optical and dielectric features of PVC/ZnCo2O4/MWCNTs/TBAI polymers for optoelectronic and energy storage applications

Abstract

Zinc cobalt oxide is considered a highly desirable substance for use in a wide range of applications, particularly supercapacitors. In this study, polyvinyl chloride/zinc cobalt oxide/multi-walled carbon nanotubes/x wt % tetrabutylammonium iodide (PVC/ZnCo2O4/MWCNTs/x wt % TBAI) composite polymers were fabricated using casting and hydrothermal approaches. The resulting composites were then analyzed to determine their structure, optical properties, and dielectric characteristics. The structure of ZnCo2O4 and PVC/ZnCo2O4/MWCNTs/x wt.% TBAI were studied using the X-ray diffraction technique. The morphologies of doped polymer were investigated using SEM technique. The impact of ZnCo2O4/MWCNTs/x wt.% TBAI filler samples on the linear and nonlinear optical properties of PVC polymer has been analyzed through UV diffused reflectance measurements. The doped samples could serve as effective shields against ultraviolet radiation across different wavelengths (UVA, UVB, UVC) and a highly effective material for absorbing solar energy in solar cells. The lowest optical energy gap values are attained (3.77, 3.03) and (3.32, 2.55) eV for the direct and indirect optical band gaps in PVC/ZnCo2O4/MWCNTs/3 wt% TBAI polymer, respectively. The largest refractive index value at 600 nm was observed in the doped polymer with 6 wt% TBAI. The fluorescence emission spectra and dielectric properties of the PVC/ZnCo2O4/MWCNTs/x wt.% TBAI polymers are also studied. The highest electrical dielectric constant was achieved in the ZnCo2O4/MWCNTs/9 wt% TBAI polymer. It follows that the PVC/ZnCo2O4/MWCNTs/x wt % TBAI has the ability to open up new possibilities for use in optoelectronic devices.