Abstract

The photometric properties of an radio frequency (RF)-based sputtering plasma source were monitored through optical spectroscopy. The colour of the plasma source was deduced based on conventional chromaticity index analysis and it was compared to the direct spectral data plots of the emission peaks to investigate the possibility of characterising the plasma based on its specific colour and exploring the potential of defining a new method by which the plasma sputtering process can be addressed based on the plasma colour parameters. The intention of this investigation is to evaluate the possibility of simplifying the monitoring and assessment of the sputtering process for applied scientists operating plasma sputter deposition systems. We demonstrate a viable potential for this technique in terms of providing information regarding the stability of the plasma, chamber pressure, and plasma power; however, further work is underway to verify and assess a relationship between the quality of the thin film coating and the colour characteristics of the deposition plasma. Here, we only focus on the feasibility of such an approach and demonstrate interesting observations. We observed a linear relationship between the colour functions and the plasma power, while the stability of the sputtering plasma can be assessed based on the plasma colour functions. The colour functions also follow a unique pattern when the working gas pressure is increased.

Highlights

  • Transparent conductive oxides (TCO) are materials that have attracted a significant amount of interests due to their vast application areas

  • They are an essential part of various optoelectronic devices, solar cell modules, light emitting diodes, and flexible electronics that involve optical elements and the physical vapor deposition (PVD) viz. sputtering under vacuum is one of the methods of depositing a range of materials as a thin film coating, mobile phone touch screens, perovskite solar cells, and OLEDs are examples of technologies that rely on TCOs [1]

  • We focused on the chromaticity of the emission, parallel to these studies we obtained the optical emission spectroscopy of the plasma, and here we shall demonstrate studies we obtained the optical emission spectroscopy of the plasma, and here we shall demonstrate the results that are associated with the experiments involving only the Argon gas as a comparative the results that are associated with the experiments involving only the Argon gas as a comparative guide to enable to discuss the observations seen through through chromaticity chromaticity analysis

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Summary

Introduction

Transparent conductive oxides (TCO) are materials that have attracted a significant amount of interests due to their vast application areas. They are an essential part of various optoelectronic devices, solar cell modules, light emitting diodes, and flexible electronics that involve optical elements and the physical vapor deposition (PVD) viz. Researchers who apply this technique for TCO preparation usually report their findings by stating the condition of the sputtering process, such as chamber pressure, plasma power and the gas composition of the chamber during deposition. We believe there is another way Coatings 2019, 9, 315; doi:10.3390/coatings9050315 www.mdpi.com/journal/coatings

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