Abstract

Abstract Optical absorption spectrum of Cr3+ ions doped in sodium ammonium sulphate dihydrate single crystal has been studied both at room and liquid nitrogen temperatures. The observed bands were explained satisfactorily assuming octahedral symmetry for the Cr3+ ion in the crystal. The crystal field parameters Dq = 1750 cm−1, B = 735 cm−1 and C = 3220 cm−1 are found to give a good fit to the observed band positions.

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