Abstract

A iodo-terminated polystyrene (PS-I) synthesized by reverse iodine transfer polymerization (RITP) was directly used as macroinitiator in the cationic ring-opening polymerization of 2-methyl-2-oxazoline to afford a water-soluble diblock copolymer. This is the first example of combination of RITP and CROP in macromolecular engineering.

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