One-Pot Green Synthesis of Ag-Decorated SnO2 Microsphere: an Efficient and Reusable Catalyst for Reduction of 4-Nitrophenol

Abstract

In this paper, hierarchical Ag-decorated SnO2 microspheres were synthesized by a facile one-pot hydrothermal method. The resulting composites were characterized by XRD, SEM, TEM, XPS, BET, and FTIR analysis. The catalytic performances of the samples were evaluated with the reduction of 4-nitrophenol to 4-aminophenol by potassium borohydride (KBH4) as a model reaction. Time-dependent experiments indicated that the hierarchical microspheres assembled from SnO2 and Ag nanoparticles can be formed when the react time is less than 10 h. With the increase of hydrothermal time, SnO2 nanoparticles will self-assemble into SnO2 nanosheets and Ag nanoparticles decorated SnO2 nanosheets were obtained. When evaluated as catalyst, the obtained Ag-decorated SnO2 microsphere prepared for 36 h exhibited excellent catalytic performance with normalized rate constant (κnor) of 6.20 min−1g−1L, which is much better than that of some previous reported catalysts. Moreover, this Ag-decorated SnO2 microsphere demonstrates good reusability after the first five cycles. In addition, we speculate the formation mechanism of the hierarchical Ag-decorated SnO2 microsphere and discussed the possible origin of the excellent catalytic activity.