Abstract
A new molybdenum(V) cobalt phosphate, [Co(H2O)6]{[Co(H2O)5]2Co2[(Mo16O32)CO16(HPO4)14(PO4)10(H2O)15]}·38H2O (1), has been prepared under hydrothermal condition, which displays a nonplanar two-dimensional inorganic framework constructed from [(Mo16O32)Co16(HPO4)14(PO4)10(H2O)15]10− wheel clusters and tetrahedral CoO4 linkers. Each wheel forms by the linking of {Co4O16} tetramers and {Mo4O19} tetramers through {PO4} groups in turn, and concurrently has two pendant Co(H2O)5 groups. The susceptibility analysis shows that the d1 electrons in the MoV dimers are spin-paired and the dominant antiferromagnetic behavior is originated from the 21 high-spin CoII ions in 1.
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