Abstract
One three-dimensional Gd(III) coordination polymer with 1,2-phenylenediacetate (PDA2−), [Gd2(PDA)3(H2O)2]·3H2O (1), has been successfully synthesized and characterized. Single crystal X-ray diffraction analysis shows that 1 consists of 1D wave Gd-based chain unit and PDA2− linker. Magnetic studies suggest the presence of ferromagnetic Gd⋯Gd coupling in the 1D chain unit of 1. Meanwhile, 1 has a significant cryogenic magnetocaloric effect with the maximum −ΔSm of 33.44 at 2K and 7T.
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