Abstract

A new heterogeneous palladium catalyst has been synthesized by one-step encapsulation in nanoporous metal-organic framework Cu2(BDC)2(DABCO) (BDC = 1,4-benzenedicarboxylate, DABCO = 1,4-diazabicyclo[2.2.2]octane) under a temperature control program. Supported Pd nanoparticles (Pd-NPs@Cu2(BDC)2(DABCO)) were characterized by X-ray diffraction, BET analysis, field emission scanning electron microscopy, transmission electron microscopy, inductively coupled plasma atomic emission and X-ray photoelectron spectroscopy (XPS). The Highly dispersed Pd particles (Pd-NPs@Cu2(BDC)2(DABCO)) offered a very efficient catalytic activity towards the Suzuki–Miyaura cross-coupling reaction.

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