One-step preparation of Fe/N co-doped porous biochar for chromium(VI) and bisphenol a decontamination in water: Insights to co-activation and adsorption mechanisms

Abstract

Herein, magnetic nitrogen doped porous biochar (Fe/N-PBC) was prepared by mixing KHCO3, K2FeO4 and CO(NH2)2 through one-step pyrolysis, and was employed for adsorbing Cr(VI) and BPA in water. The whole co-activated process was accompanied with pore-forming, carbon thermal reduction and element doping. Specifically, the developed microporous structures and high surface area of Fe/N-PBC (1093.68 m2/g) were achieved under synergistic activation of KHCO3 and K2FeO4. Meanwhile, carbon thermal reduction process successfully converted K2FeO4 to Fe0 with introduction of heterocyclic-N (pyrrolic N and pyridinic N) structures by CO(NH2)2 doping. Fe/N-PBC exhibited outstanding uptake for Cr(VI) (340.96 mg/g) and BPA (355.14 mg/g), and possessed favorable regeneration properties after three cycles. Notably, the high-performance Cr(VI) removal was associated to reduction, electrostatic interaction, complexation, pore filling and ion exchange, while pore filling, hydrogen-bonding interaction and π-π stacking were responsible for BPA binding. This work presents reasonable design of Fe/N-carbon materials for Cr(VI)/BPA polluted water remediation.