One-step natural pyrite-assisted mechanochemical detoxification of Cr(VI) in soda ash Chromite Ore Processing Residue: Effectiveness, mechanisms, and life cycle analysis

Abstract

Traditional wet and dry Chromite Ore Processing Residue (COPR) detoxification methods consume acid for pH adjustment and produce greenhouse gasses (CO2), yielding potential secondary pollution. It is imperative to develop an environmentally-friendly, efficient, and effective method for COPR treatment. This study reported the one-step natural pyrite-assisted mechanochemical detoxification of Cr(VI) in COPR. Under optimal conditions (i.e., the pyrite/COPR mass ratio of 5% and mechanochemical treatment at 600 rev./min for 2.5 h), Cr(VI) in COPR was efficiently reduced and immobilized, and the leaching concentration of total Cr met the regulatory limit of 5 mg/L. The X-ray absorption near-edge structure (XANES) analysis further verified that the Cr(VI) in treated COPR was 100% reduced to Cr(III). Potential mechanism could be that the enclosed non-exchangeable Cr(VI) in the chromite matrix was exposed to the COPR particle surface under the mechanical action; then, the redox reaction between pyrite and Cr(VI) were induced and enhanced through accumulated crystal defects and generated new surfaces with dangling bonds under mechanical forces. Life cycle assessment (LCA) results highlight that the high energy input is the major contributor eliciting environmental impacts for this current technology. More efficient and cleaner energy supplies should be sought alternatively to overcome the overall sustainability.