One-Step Hydrothermal Synthesis of 3D Interconnected rGO/In2O3 Heterojunction Structures for Enhanced Acetone Detection

Abstract

Acetone detection is of great significance for environmental monitoring or diagnosis of diabetes. Nevertheless, fast and sensitive detection of acetone at low temperatures remains challenging. Herein, a series of rGO-functionalized three-dimensional (3D) In2O3 flower-like structures were designed and synthesized via a facile hydrothermal method, and their acetone-sensing properties were systematically investigated. Compared to the pure 3D In2O3 flower-like structures, the rGO-functionalized 3D In2O3 flower-like structures demonstrated greatly improved acetone-sensing performance at relatively low temperatures. In particular, the 5-rGO/In2O3 sensor with an optimized decoration exhibited the highest response value (5.6) to 10 ppm acetone at 150 °C, which was about 2.3 times higher than that of the In2O3 sensor (2.4 at 200 °C). Furthermore, the 5-rGO/In2O3 sensor also showed good reproducibility, a sub-ppm-level detection limit (1.3 to 0.5 ppm), fast response and recovery rates (3 s and 18 s, respectively), and good long-term stability. The extraordinary acetone-sensing performance of rGO/In2O3 composites can be attributed to the synergistic effect of the formation of p-n heterojunctions between rGO and In2O3, the large specific surface area, the unique flower-like structures, and the high conductivity of rGO. This work provides a novel sensing material design strategy for effective detection of acetone.