One-pot radiolytically synthesized reduced graphene oxide-gold nanoparticles composites and exploration in energy storage

Abstract

Graphene and its composites are of primary importance, particularly in the field of energy storage. Numerous bottom-up and top-down methods have been proposed in the literature to produce these materials with enhanced physicochemical properties. Recently, an innovative and green methodology was developed based on ionizing radiation, allowing the quantitative synthesis of graphene oxide-based materials. With the aim to extend this strategy for the preparation of hybrid nanomaterials, the objective of this work was the one-pot synthesis of nanocomposites composed of reduced graphene oxide – gold nanoparticles (rGO-AuNPs) via gamma ray-induced radiolytic reduction. UV–Vis Absorption Spectroscopy, Fourier Transform Infrared Spectroscopy, Raman Spectroscopy and X-ray Photoemission Spectroscopy were utilized to comprehensively evaluate the reduction degree of graphene oxide and the formation of gold nanoparticles. Atomic Force Microscopy and Scanning Electron Microscopy were employed to obtain the morphological and topographical information on synthesized nanocomposites. Thermal properties were investigated by Thermogravimetric Analysis and electrical properties were investigated using Cyclic Voltammetry and Potentiostatic Charge and Discharge method. The results demonstrated the successful reduction of graphene oxide and gold ions through the drastic transformation of oxygen-containing functional groups and the formation of gold nanoparticles. Electrical characterization results highlighted the excellent electrical properties of radiosynthesized rGO-AuNPs composites and their great potential for supercapacitance application.