Abstract

AbstractThe ternary catalyst systems based on activated silica, aluminum alkyl, and titanium tetrachloride were polymerized in an ethylene gas‐phase polymerization process, and further studied using ESR spectroscopy. Two types of titanium (III) ESR‐active centers were observed and a linear dependence between the concentration of that characterized by a rhombic anisotropic signal with g1 = 1.962, g2 = 1.945, and g3 = 1.913 values and catalyst productivity was found. © 1993 John Wiley & Sons, Inc.

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