Abstract
Abstract One novel organic–inorganic hybrid materials with 4,4′-bipy ligands and copper chlorine coordination polymers as linkers, with new topology, {[Cu I (4,4′-bipy)] 10 Cl 2 (SiW 12 O 40 ) 2 }·6H 2 O ( 1 ) (4,4′-bipy = 4,4′-bipyridine), has been hydrothermally synthesized. The single crystal X-ray structural analysis reveals that the structure of 1 is constructed from classical Keggin anions and [Cu I (4,4′-bipy)] cations into a novel, three-dimensional (3D) polyoxometalates (POMs)based network. From the topological view, compound 1 is a novel (3.4 4 .5 2 .6 3 )(3 2 .4 4 .5 6 .6 9 ) topology. The electrochemical and photocatalysis properties of 1 have been investigated in details.
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