One‐dimensional molecular co‐crystal alloys capable of full‐color emission for low‐loss optical waveguide and optical logic gate

Abstract

AbstractThe luminescence color of molecule‐based photoactive materials is the key to the applications in lighting and optical communication. Realizing continuous regulation of emission color in molecular systems is highly desirable but still remains a challenge due to the individual emission band of purely organic molecules. Herein, a novel alloy strategy based on molecular co‐crystals is reported. By adjusting the molar ratio of pyrene (Py) and fluorathene (Flu), three types of molecular co‐crystal alloys (MCAs) assemblies are prepared involving Py‐Flu‐OFN‐x%, Py‐Flu‐TFP‐x%, Py‐Flu‐TCNB‐x%. Multiple energy level structure and Förster resonance energy transfer (FRET) process endow materials with tunable full‐spectra emission color in visible region. Impressively, these MCAs and co‐crystals can be successfully applied to low optical loss waveguide and optical logic gate by virtue of all‐color luminescence from blue across green to red, together with smooth surface of one‐dimensional microrods, which show promising applications as continuous light emitters for advance photonics applications.