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Abstract
Normal coordinate calculations have been carried out for thiophosphoryl fluoride (SPF 3 ) using a simple valence force field and several modified valence force fields. These calculations have shown that the a 1 vibrations of SPF 3 cannot be assigned in a simple way to bending or stretching vibrations. The degenerate e vibrations on the other hand can be assigned to PF stretching FPF bending and SPF bending vibrations.
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