Abstract
Abstract The molecular g-tensor and the magnetic susceptibility anisotropy of cyclopropane were deter mined by a microwave Fourier transform study of the rotational Zeeman effect of its 1,1-dideuterated isotopomer. The results g⊥ = 0.02675(23), g∥ = 0.06998(23), and ξ⊥ - ξ ∥ = 8.80(31) · 10-6 erg G-2 mol-2 are in agreement with values determinea indirectly from van der Waals complexes. This finding provides experimental evidence that in van der Waals molecules additivity rules might hold to a high degree of approximation for both types of tensors. Rotational Zeeman effect studies of van der Waals complexes may thus provide valuable extra information on their structures.
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