Abstract

The oxidation kinetics of two metallic glasses have been studied by ellipsometry and Auger Electron spectroscopy. The presence of chromium in Fe-based alloys has a marked influence on the corrosion film formed and on the kinetics of film formation. The chromium-free alloy shows piecemeal parabolic oxide growth; this is transformed into a logarithmic growth law for the chromium concentration studied. The influence of moisture on the kinetics of film formation has also been studied.

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